In mainland Britain, you are never more than 52 miles from a library.
This fact is calculated from data recorded in OpenStreetMap.
The point that achieves the furthest distance from a library is here, with the nearest to it being this.
If you know of a library that disproves the claim, you can edit OpenStreetMap (here's how) to make sure that item is listed on the map. (NB this website is refreshed occasionally from OpenStreetMap, but not instantly.)